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A simple formulation of the CH2O photolysis quantum yields

Item

Title (Dublin Core)

A simple formulation of the CH2O photolysis quantum yields

Description (Dublin Core)

New expressions for the wavelength-dependent photolysis quantum yields of CH<sub>2</sub>O, &Phi;<sub><i>j</i></sub>, are presented. They are based on combinations of functions of the type <i>A<sub>i</sub></i>/(1+exp[&minus;(1/&lambda; &minus; 1/&lambda;<sub>0<i>i</i></sub>)/<i>b<sub>i</sub></i>]). The parameters <i>A<sub>i</sub></i>, <i>b<sub>i</sub></i>, and &lambda;<sub>0<i>i</i></sub> which have a physical meaning, are obtained by fits to the measured &Phi;<sub><i>j</i></sub> data available from literature. The altitude dependence of the photolysis frequencies resulting from the new quantum yield expressions are compared to those derived from the &Phi;<sub><i>j</i></sub> recommended by JPL and IUPAC.

Creator (Dublin Core)

Röth, E.-P.
Ehhalt, D. H.

Date (Dublin Core)

2018-09-10

Type (Dublin Core)

Text

Format (Dublin Core)

application/pdf

Identifier (Dublin Core)

10.5194/acp-15-7195-2015
https://acp.copernicus.org/articles/15/7195/2015/

Source (Dublin Core)

eISSN: 1680-7324

Language (Dublin Core)

eng
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