The decrease in mid-stratospheric tropical ozone since 1991
Item
Title (Dublin Core)
The decrease in mid-stratospheric tropical ozone since 1991
Description (Dublin Core)
While global stratospheric O<sub>3</sub> has begun to recover, there are localized regions where O<sub>3</sub> has decreased since 1991. Specifically, we use measurements from the Halogen Occultation Experiment (HALOE) for the period 1991–2005 and the NASA Aura Microwave Limb Sounder (MLS) for the period 2004–2013 to demonstrate a significant decrease in O<sub>3</sub> near ~ 10 hPa in the tropics. O<sub>3</sub> in this region is very sensitive to variations in NO<sub><i>y</i></sub>, and the observed decrease can be understood as a spatially localized, yet long-term increase in NO<sub><i>y</i></sub>. In turn, using data from MLS and from the Atmospheric Chemistry Experiment (ACE), we show that the NO<sub><i>y</i></sub> variations are caused by decreases in N<sub>2</sub>O which are likely linked to long-term variations in dynamics. To illustrate how variations in dynamics can affect N<sub>2</sub>O and O<sub>3</sub>, we show that by decreasing the upwelling in the tropics, more of the N<sub>2</sub>O can photodissociate with a concomitant increase in NO<sub><i>y</i></sub> production (via N<sub>2</sub>O + O(<sup>1</sup>D) → 2NO) at 10 hPa. Ultimately, this can cause an O<sub>3</sub> decrease of the observed magnitude.
Creator (Dublin Core)
Nedoluha, G. E.
Siskind, D. E.
Lambert, A.
Boone, C.
Date (Dublin Core)
2018-09-14
Type (Dublin Core)
Text
Format (Dublin Core)
application/pdf
Identifier (Dublin Core)
10.5194/acp-15-4215-2015
https://acp.copernicus.org/articles/15/4215/2015/
Source (Dublin Core)
eISSN: 1680-7324
Language (Dublin Core)
eng
