Index Geophysics

Parameterisation and impact of aerosol uptake of HO2 on a global tropospheric model

HO₂ is an important atmospheric trace gas, whose sink to aerosol is poorly understood yet significant. Previous parameterisations of the rate of uptake have been limited by the lack of laboratory studies. This paper creates a parameterisation for γ_HO₂ based on the available laboratory studies. The calculated global mean γ_HO₂ is 0.028, significantly lower than previous work (0.2). Modelled concentrations of HO₂ show significant regional sensitivity to the value of γ_HO₂ (up to +106% at the surface with the parameterisation of γ_HO₂ in this work as compared with a value of 0.2), but global sensitivity is small (+3.2%). The modelled response in O₃ is also highly regional, being up to +27% at the surface over China, and only +0.3% globally (with the parameterisation of γ_HO₂ in this work as compared with a value of 0.2). The impact of γ_HO₂ on sulfate is more complex, with up to +16% over China and −5% over high latitudes, resulting in a global change of +1.2% (with the parameterisation of γ_HO₂ in this work as compared with a value of 0.2). Uncertainty in the reaction mechanism and hence products (previously assumed to be H₂O₂) impacts the processing of sulfur and hence aerosol loads. Further laboratory studies are desirable to constrain the rate of reaction and to elucidate the reaction mechanism and products.

Macintyre, H. L.

Evans, M. J.

2018-01-15

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application/pdf

10.5194/acp-11-10965-2011

https://acp.copernicus.org/articles/11/10965/2011/

eISSN: 1680-7324

eng