Heterogeneous uptake of gaseous hydrogen peroxide by Gobi and Saharan dust aerosols: a potential missing sink for H2O2 in the troposphere
Item
Title (Dublin Core)
Heterogeneous uptake of gaseous hydrogen peroxide by Gobi and Saharan dust aerosols: a potential missing sink for H2O2 in the troposphere
Description (Dublin Core)
The first direct laboratory measurements of gaseous hydrogen peroxide uptake by authentic Gobi and Saharan dust aerosol particles as a function of relative humidity (RH) have been carried out in an entrained aerosol flow tube coupled to a chemical ionization mass spectrometer. Gobi dust shows uptake coefficients, γ<sub>H<sub>2</sub> O<sub>2</sub></sub> = (3.33±0.26) ×10<sup>−4</sup> at 15% RH rising to γ<sub>H<sub>2</sub> O<sub>2</sub></sub> = (6.03±0.42) ×10<sup>−4</sup> at 70% RH; the corresponding values for Saharan dust are systematically higher (γ<sub>H<sub>2</sub> O<sub>2</sub></sub> = (6.20±0.22)×10<sup>−4</sup> at 15% RH rising to γ<sub>H<sub>2</sub> O<sub>2</sub></sub> = (9.42±0.41) ×10<sup>−4</sup> at 70% RH). High resolution X-ray photoelectron spectroscopy (XPS) measurements of the surface chemical composition of the two mineral dust samples together with published water adsorption isotherms of their principal constituents enables rationalization of these observations, which are relevant to nighttime tropospheric chemistry. A box model study performed by incorporating the experimentally determined data set reveals that uptake of H<sub>2</sub>O<sub>2</sub> onto dust can be an important loss process for this species which has been, until now, poorly constrained.
Creator (Dublin Core)
Pradhan, M.
Kyriakou, G.
Archibald, A. T.
Papageorgiou, A. C.
Kalberer, M.
Lambert, R. M.
Date (Dublin Core)
2018-01-15
Type (Dublin Core)
Text
Format (Dublin Core)
application/pdf
Identifier (Dublin Core)
10.5194/acp-10-7127-2010
https://acp.copernicus.org/articles/10/7127/2010/
Source (Dublin Core)
eISSN: 1680-7324
Language (Dublin Core)
eng
