Seasonal variations of concentrations and optical properties of water soluble HULIS collected in urban environments
Item
Title (Dublin Core)
Seasonal variations of concentrations and optical properties of water soluble HULIS collected in urban environments
Description (Dublin Core)
Major contributors to the organic aerosol include water-soluble macromolecular compounds (e.g. HULIS<sub>WS</sub>: Water Soluble Humic LIke Substances). The nature and sources of HULIS<sub>WS</sub> are still largely unknown. This work is based on a monitoring in six different French cities performed during summer and winter seasons. HULIS<sub>WS</sub> analysis was performed with a selective method of extraction complemented by carbon quantification. UV spectroscopy was also applied for their chemical characterisation. HULIS<sub>WS</sub> carbon represent an important contribution to the organic aerosol mass in summer and winter, as it accounts for 12–22% of Organic Carbon and 34–40% of Water Soluble Organic Carbon. We found strong differences in the optical properties (specific absorbance at 250, 272, 280 nm and E2/E3 ratio) and therefore in the chemical structure between HULIS<sub>WS</sub> from samples of summer- and wintertime. These differences highlight different processes responsible for emissions and formation of HULIS<sub>WS</sub> according to the season, namely biomass burning in winter, and secondary processes in summer. Specific absorbance can also be considered as a rapid and useful indicator of the origin of HULIS<sub>WS</sub> in urban environment.
Creator (Dublin Core)
Baduel, C.
Voisin, D.
Jaffrezo, J.-L.
Date (Dublin Core)
2018-01-15
Type (Dublin Core)
Text
Format (Dublin Core)
application/pdf
Identifier (Dublin Core)
10.5194/acp-10-4085-2010
https://acp.copernicus.org/articles/10/4085/2010/
Source (Dublin Core)
eISSN: 1680-7324
Language (Dublin Core)
eng
