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Optical and geometrical characteristics of cirrus clouds over Thessaloniki, Greece (40.6° N, 22.9° E) have been determined from the analysis of lidar and radiosonde measurements performed during the period from 2000 to 2006. Cirrus clouds are generally observed in a mid-altitude region ranging from 8.6 to 13 km, with mid-cloud temperatures in the range from −65° to −38°C. The cloud thickness generally ranges from 1 to 5 km and 38{%} of the cases studied have thickness between 2 and 3 km. The retrieval of optical depth and lidar ratio of cirrus clouds is performed using three different methods, taking into account multiple scattering effect. The mean optical depth is found to be 0.31±0.24 and the corresponding mean lidar ratio is 30±17 sr following the scheme of Klett-Fernald method. Sub-visual, thin and opaque cirrus clouds are observed at 3%, 57% and 40% of the measured cases, respectively. A comparison of the results obtained between the three methods shows good agreement. The multiple scattering errors of the measured effective extinction coefficients range from 20 to 60%, depending on cloud optical depth. The temperature and thickness dependencies on optical properties have also been studied in detail. A maximum mid-cloud depth of ~3.5 km is found at temperatures around ~−47.5°C, while there is an indication that optical depth and mean extinction coefficient increases with increasing mid-cloud temperature. A correlation between optical depth and thickness was also found. However, no clear dependence of the lidar ratio values on the cloud temperature and thickness was found.
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An 1.5-level-closure and 3-D non-stationary atmospheric boundary layer (ABL) model and a radiation transfer model with the output of Weather Research and Forecast (WRF) Model and lidar AML-1 are employed to simulate the dust aerosol radiative effect and its influence on ABL in Beijing for the period of 23–26 January 2002 when a dust storm occurred. The simulation shows that daytime dust aerosol radiative effect heats up the ABL at the mean rate of about 0.68 K/h. The horizontal wind speed from ground to 900 m layer is also overall increased, and the value changes about 0.01 m/s at 14:00 LT near the ground. At night, the dust aerosol radiative effect cools the ABL at the mean rate of −0.21 K/h and the wind speed lowers down at about −0.19 m/s at 02:00 LT near the ground.
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This paper examines the effect of the total solar eclipse of 29 March 2006 on meteorological variables across Greece. Integrated micrometeorological measurements were conducted at Kastelorizo, a small island within the path of totality, and other sites within the Greek domain, with various degrees of solar obscuration. The observations showed a dramatic reduction in the incoming global radiation and subsequent, pronounced changes in surface air temperature with the lowest temperature values occurring about 15 min after the full phase. The amplitude of the air temperature drop was not analogous to the obscuration percentage but was principally determined by the surrounding environment (mainly the sea influence), the background meteorological conditions and local cloudiness. Surface wind-speed decreased in most sites as a result of the cooling and stabilization of the atmospheric boundary layer. This perturbation provided a unique opportunity to apply a sensitivity analysis on the effect of the eclipse to the Weather Research and Forecast (WRF) numerical mesoscale meteorological model. Strong anomalies, not associated with a dynamic response, were simulated over land especially in surface air temperature. The simulated temperature drop pattern was consistent with the observations.
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The emissions of NO<sub>x</sub> (defined as NO (nitric oxide) + NO<sub>2</sub> (nitrogen dioxide)) and hydrogen cyanide (HCN), per unit amount of fuel burned, from fires in the pine forests that dominate the mountains surrounding Mexico City (MC) are about 2 times higher than normally observed for forest burning. The ammonia (NH<sub>3</sub>) emissions are about average for forest burning. The upper limit for the mass ratio of NO<sub>x</sub> to volatile organic compounds (VOC) for these MC-area mountain fires was ~0.38, which is similar to the NO<sub>x</sub>/VOC ratio in the MC urban area emissions inventory of 0.34, but much larger than the NO<sub>x</sub>/VOC ratio for tropical forest fires in Brazil (~0.068). The nitrogen enrichment in the fire emissions may be due to deposition of nitrogen-containing pollutants in the outflow from the MC urban area. This effect may occur worldwide wherever biomass burning coexists with large urban areas (e.g. the tropics, southeastern US, Los Angeles Basin). The molar emission ratio of HCN to carbon monoxide (CO) for the mountain fires was 0.012±0.007, which is 2–9 times higher than widely used literature values for biomass burning. The ambient molar ratio HCN/CO in the MC-area outflow is about 0.003±0.0003. Thus, if only mountain fires emit significant amounts of HCN, these fires may be contributing about 25% of the CO production in the MC-area (~98–100 W and 19–20 N). Comparing the PM<sub>10</sub>/CO and PM<sub>2.5</sub>/CO mass ratios in the MC Metropolitan Area emission inventory (0.0115 and 0.0037) to the PM1/CO mass ratio for the mountain fires (0.133) then suggests that these fires could produce as much as ~79–92% of the primary fine particle mass generated in the MC-area. Considering both the uncertainty in the HCN/CO ratios and secondary aerosol formation in the urban and fire emissions implies that about 50±30% of the "aged" fine particle mass in the March 2006 MC-area outflow could be from these fires.
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The present study delineates the characteristics of Stratospheric Sudden Warming (SSW) events observed over the Observatoire de Haute Provence (OHP: 44° N, 6° E). The study uses 20 years of Rayleigh LiDAR temperature measurements for the period, 1982–2001, which corresponds to 2629 daily temperature profiles. Characteristics of warming events, such as type of warming (major and minor), magnitude of warming, height of occurrence and day period of occurrence are presented with emphasis on wave propagation and isentropic transport conditions. The major and minor warming events are classified with respect to temperature increase and reversal in the zonal wind direction in the polar region using reanalysis data from the National Centre for Environmental Prediction (NCEP). SSWs occur with a mean frequency of 2.15 events per winter season. The percentage of occurrence of major and minor warming events are found to be ~23% and ~77%, respectively. The observed major and minor SSW is associated with a descent of the stratopause layer by −6 to 6 km range. The heights of occurrences of major SSWs are distributed between 38 km and 54 km with magnitudes in the 12.2–35.7 K temperature range, while minor SSW occurrences appear in the 42–54 km range, closer to the usual stratopause layer (~47 km) and with a slightly larger range of temperature magnitude (10.2–32.8 K). The observed major and minor events are examined in connection with Quasi-Biennial Oscillation (QBO) phases.
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The chemistry climate model ECHAM5/MESSy1 (E5/M1) in a setup extending from the surface to 80 km with a vertical resolution of about 600 m near the tropopause with nudged tropospheric meteorology allows a direct comparison with satellite data of chemical species at the same time and location. Here we present results out of a transient 10~years simulation for the period of the Antarctic vortex split in September 2002, where data of MIPAS on the ENVISAT-satellite are available. For the first time this satellite instrument opens the opportunity, to evaluate all stratospheric nitrogen containing species simultaneously with a good global coverage, including the source gas N<sub>2</sub>O and ozone which allows an estimate for NO<sub>x</sub>-production in the stratosphere. We show correlations between simulated and observed species in the altitude region between 10 and 50 hpa for different latitude belts, together with the Probability Density Functions (PDFs) of model results and observations. This is supplemented by global maps on pressure levels showing the comparison between the satellite and the simulated data sampled at the same time and location. We demonstrate that the model in most cases captures the partitioning in the nitrogen family, the diurnal cycles and the spatial distribution within experimental uncertainty. This includes even variations due to tropospheric clouds. There appears to be, however, a problem to reproduce the observed nighttime partitioning between N<sub>2</sub>O<sub>5</sub> and NO<sub>2</sub> in the middle stratosphere using the recommended set of reaction coefficients and photolysis data.
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Our current understanding of secondary organic aerosol (SOA) formation is limited by our knowledge of gaseous secondary organics involved in gas/particle partitioning. The objective of this study is to explore (i) the potential for products of multiple oxidation steps contributing to SOA, and (ii) the evolution of the SOA/VOC/NO<sub>x</sub> system. We developed an explicit model based on the coupling of detailed gas-phase oxidation schemes with a thermodynamic condensation module. Such a model allows prediction of SOA mass and speciation on the basis of first principles. The SOA/VOC/NO<sub>x</sub> system is studied for the oxidation of 1-octene under atmospherically relevant concentrations. In this study, gaseous oxidation of octene is simulated to lead to SOA formation. Contributors to SOA formation are shown to be formed via multiple oxidation steps of the parent hydrocarbon. The behaviour of the SOA/VOC/NO<sub>x</sub> system simulated using the explicit model agrees with general tendencies observed during laboratory chamber experiments. This explicit modelling of SOA formation appears as a useful exploratory tool to (i) support interpretations of SOA formation observed in laboratory chamber experiments, (ii) give some insights on SOA formation under atmospherically relevant conditions and (iii) investigate implications for the regional/global lifetimes of the SOA.
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A meteorological case study for the impact of inertia-gravity waves on surface meteorology is presented. The large-scale environment from 17 to 19 December 1999 was dominated by a poleward breaking Rossby wave transporting subtropical air over the North Atlantic Ocean upward and north-eastward. The synoptic situation was characterized with an upper tropospheric jet streak passing Northern Europe. The unbalanced jet spontaneously radiated inertia-gravity waves from its exit region. Near-inertial waves appeared with a horizontal wavelength of about 200 km and an apparent period of about 12 h. These waves transported energy downwards and interacted with large-scale convection. <br><br> This configuration is simulated with the nonhydrostatic Fifth-Generation Mesoscale Model. Together with simplified runs without orography and moisture it is demonstrated that the imbalance of the jet (detected with the cross-stream ageostrophic wind) and the deep convection (quantified with the latent heat release) are forcing inertia-gravity waves. This interaction is especially pronounced when the upper tropospheric jet is located above a cold front at the surface and supports deep frontal convection. Weak indication was found for triggering post-frontal convection by inertia-gravity waves. <br><br> The realism of model simulations was studied in an extended validation study for the Baltic Sea region. It included observations from radar (DWDPI, BALTRAD), satellite (GFZGPS), weather stations (DWDMI) and assimilated products (ELDAS, MESAN). The detected spatio-temporal patterns show wind pulsations and precipitation events at scales corresponding to those of inertia-gravity waves. In particular, the robust features of strong wind and enhanced precipitation near the front appeared with nearly the same amplitudes as in the model. In some datasets we found indication for periodic variations in the post-frontal region. <br><br> These findings demonstrate the impact of upper tropospheric jet-generated inertia-gravity waves on the dynamics of the boundary layer. It also gives confidence to models, observations and assimilation products for covering such processes. In an application for the Gotland Basin in the Baltic Sea, the implications of such mesoscale events on air-sea interaction and energy and water budgets are discussed.
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Experimental and modelling results of the dynamics of a sea-breeze event and its effects on the three-dimensional (3-D) redistribution of the gaseous SO<sub>2</sub> are presented within the framework of a particularly flat and industrialized coastal area of the North Sea. The measurements were carried out at ground level with the stations of the local air quality monitoring agency and with two optical remote sensing instruments. The remote sensing setup consisted of a lidar and a sodar whose measurements allowed us to determine the layers of the lower troposphere during a sea-breeze event up to 1400 m height. The experimental results and measurements of industrial SO<sub>2</sub> in the atmosphere are compared to the numerical simulations of the 3-D atmospheric non-hydrostatic chemistry model Meso-NH-C. The transport and the dispersion of gaseous SO<sub>2</sub> are studied above the neighbouring industrial and urban areas. We show how the evolution and the redistribution of the SO<sub>2</sub> concentrations at ground level are related to the structure and the dynamics of the sea breeze. The gaseous SO<sub>2</sub> is brought back inland as soon as the sea breeze commences, mixed inner the thermal internal boundary layer and transported inland by the gravity current up to the sea-breeze front, where gases and particles are uplifted. The elevation of the polluted air masses by the sea-breeze system favours the nucleation of the emitted compounds due to the increase of the relative humidity in the uplifted layer. We show how the dynamical conditions during and after the sea breeze lead to storage of SO<sub>2</sub> near and above the emitting industrial coastal areas, and favour the formation of acidic aerosol particles.
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Changes in climate are likely to drive changes in stratospheric mixing with associated implications for changes in transport of ozone from tropical source regions to higher latitudes, transport of water vapour and source gas degradation products from the tropical tropopause layer into the mid-latitude lower stratosphere, and changes in the meridional distribution of long-lived trace gases. To diagnose long-term changes in stratospheric mixing, global monthly fields of Lyapunov exponents were calculated on the 450 K, 550 K, and 650 K isentropic surfaces by applying a trajectory model to wind fields from NCEP/NCAR reanalyses over the period 1979 to 2005. Potential underlying geophysical drivers of trends and variability in these mixing fields were investigated by applying a least squares regression model, which included basis functions for a mean annual cycle, seasonally dependent linear trends, the quasi-biennial oscillation (QBO), the solar cycle, and the El Niño Southern Oscillation (ENSO), to zonal mean time series of the Lyapunov exponents. <br><br> Long-term positive trends in mixing are apparent over southern middle to high latitudes at 450 K through most of the year, while negative trends over southern high latitudes are apparent at 650 K from May to August. Wintertime negative trends in mixing over northern mid-latitudes are apparent at 550 K and 650 K. Over low latitudes, within 40° of the equator, the QBO exerts a strong influence on mixing at all three analysis levels. This QBO influence is strongly modulated by the annual cycle and shows a phase shift across the subtropical mixing barrier. Solar cycle and ENSO influences on mixing are generally not significant. The diagnosed long-term changes in mixing should aid the interpretation of trends in stratospheric trace gases.
