-
The potential impact of CCl<sub>2</sub>FCF<sub>3</sub> (CFC-114a) and the recently observed CCl<sub>2</sub>FCCl<sub>2</sub>F (CFC-112), CCl<sub>3</sub>CClF<sub>2</sub> (CFC-112a), and CCl<sub>3</sub>CF<sub>3</sub> (CFC-113a) chlorofluorocarbons (CFCs) on stratospheric ozone and climate is presently not well characterized. In this study, the UV absorption spectra of these CFCs were measured between 192.5 and 235 nm over the temperature range 207–323 K. Precise parameterizations of the UV absorption spectra are presented. A 2-D atmospheric model was used to evaluate the CFC atmospheric loss processes, lifetimes, ozone depletion potentials (ODPs), and the associated uncertainty ranges in these metrics due to the kinetic and photochemical uncertainty. The CFCs are primarily removed in the stratosphere by short-wavelength UV photolysis with calculated global annually averaged steady-state lifetimes (years) of 63.6 (61.9–64.7), 51.5 (50.0–52.6), 55.4 (54.3–56.3), and 105.3 (102.9–107.4) for CFC-112, CFC-112a, CFC-113a, and CFC-114a, respectively. The range of lifetimes given in parentheses is due to the 2<i>σ</i> uncertainty in the UV absorption spectra and O(<sup>1</sup>D) rate coefficients included in the model calculations. The 2-D model was also used to calculate the CFC ozone depletion potentials (ODPs) with values of 0.98, 0.86, 0.73, and 0.72 obtained for CFC-112, CFC-112a, CFC-113a, and CFC-114a, respectively. Using the infrared absorption spectra and lifetimes determined in this work, the CFC global warming potentials (GWPs) were estimated to be 4260 (CFC-112), 3330 (CFC-112a), 3650 (CFC-113a), and 6510 (CFC-114a) for the 100-year time horizon.
-
Observations of turbulence are analysed for the afternoon and evening transition (AET) during the Boundary-Layer Late Afternoon and Sunset Turbulence (BLLAST) experimental field campaign that took place in Lannemezan (foothills of the Pyrenees) in summer 2011. The case of 2 July is further studied because the turbulence properties of the lower atmosphere (up to 300 m above ground level) were sampled with the Meteorological Mini Aerial Vehicle (M<sup>2</sup>AV) from turbulently mixed to stably stratified atmospheric conditions. Additionally, data from radiosoundings, 60 m tower and UHF wind profiler were taken together with the model results from a high-resolution mesoscale simulation of this case. Weak large-scale winds and clear-sky conditions were present on the studied AET case favouring the development of slope winds and mountain–plain circulations. It is found that during the AET the anisotropy of the turbulent eddies increases as the vertical motions are damped due to the stably stratified conditions. This effect is enhanced by the formation of a low-level jet after sunset. Finally, the comparison of the anisotropy ratio computed from the different sources of observations allow us to determine the most relevant scales of the motion during the AET in such a complex terrain region.
-
A fair fraction of Pc1 pulsation events observed on the ground includes more than one simultaneous pulsation band. In most such multiband events the bands display different characteristics and, therefore, come from different source regions via horizontal ducting in the ionosphere. However, in this report we identify a new "coherent" subclass of multiband Pc1 events where the pearls of the simultaneous bands have the same group velocities (repetition rates) as well as dispersion and other properties, thus implying that the bands are produced by the same source. Studying one example of such a coherent multiband event in more detail, we argue that these events defy an explanation in terms of band splitting by magnetospheric heavy ions because the observed frequency gap between the bands is smaller than would result in such a case. We interpret these events to be due to the frequency dependence of the ionospheric reflection coefficient of Alfvén waves. An oscillatory frequency dependence of the coefficient is a natural consequence of the idea that the ionosphere acts as a resonator for Alfvén waves. We also discuss other predictions of this interpretation.
-
High latitude ion outflows mostly consist of upward streaming O<sup>+</sup> and He<sup>+</sup> emanating from the ionosphere. At heights above 1000 km, these flows consist of cold and hot components which resonantly scatter solar extreme ultraviolet (EUV) light, however, the ion populations respond differently to Doppler shifting resulting from the large relative velocities between the ions and the Sun. The possibility of optical detection of the Doppler effect on the scattering rate will be discussed for the O<sup>+</sup> (83.4 nm) ions. We have contrasted the EUV solar resonance images of these outflows by simulations of the 30.4 nm He<sup>+</sup> and 83.4 nm O<sup>+</sup> emissions for both quiet and disturbed geomagnetic conditions. Input data for the 1000 km level has been obtained from the EICS instrument aboard the Dynamics Explorer satellite. Our results show emission rates of 50 and 56 milli-Rayleighs at 30.4 nm for quiet and disturbed conditions and 65 and 75 milli-Rayleighs at 83.4 nm for quiet and disturbed conditions, respectively, obtained for a polar orbiting satellite and viewing radially outward. We also find that an imager at an equatorial distance of 9 R<i><sub>E</sub></i> or more is in a favourable position for detecting ion outflows, particularly when the plasmapause is depressed in latitude. However, an occultation disk is necessary to obscure the bright plasmaspheric emissions.
-
In this paper we reanalyse the set of ten major geomagnetic storms which occurred between August 1978 and December 1979. We relate them to the characteristics of the solar wind disturbances which caused them and the solar sources of such disturbances as tracked by means of interplanetary scintillation. It seems to us that the shock causing the sudden commencement and the plasma behind it with an important long-lasting B<sub>z</sub> south component (B<sub>z</sub>.
-
The spatial extent and temporal behaviour of quasi-periodic (QP) intensity modulations of 0.5-2 kHz ELF-VLF signals were investigated in a comparative study of data collected at the Antarctic stations of South Pole (<i>L</i>=14), Halley (<i>L</i>=4), and Siple (<i>L</i>=4). Frequently, the waveforms of ELF-VLF signals simultaneously received at each site were identical. Although of similar frequency structure, the waveforms of the accompanying Pc3 magnetic pulsations did not show a one-to-one association. Whereas both are dayside phenomena, QP emissions occur over a smaller range of local times, and have a maximum of occurrence later in the day closer to local noon. QP emissions are identified with the periodic modulation of the electron pitch-angle distribution by the propagation of ULF compressional fast-mode waves through a region. However, contrary to previous ideas, rising-tone emissions do not represent the frequency-time signatures of such waves. In addition to generation close to the equatorial plane, we propose an additional high-latitude source of QP emissions. These emissions are associated with regions of minimum <i>B</i> produced by the dayside compression of the magnetosphere close to the magnetopause. Model magnetic field calculations of these minimum-<i>B</i> regions as a function of magnetic local time and invariant latitude are presented.
-
A previous study, based on incoherent and coherent radar measurements, suggested that during auroral E-region electron heating conditions, the electron flow in the auroral electrojet undergoes a systematic counterclockwise rotation of several degrees relative to the <strong>E</strong>×<strong>B</strong> direction. The observational evidence is re-examined here in the light of theoretical predictions concerning E-region electron demagnetization caused by enhanced anomalous cross-field diffusion during strongly-driven Farley-Buneman instability. It is shown that the observations are in good agreement with this theory. This apparently endorses the concept of wave-induced diffusion and anomalous electron collision frequency, and consequently electron demagnetization, under circumstances of strong heating of the electron gas in the auroral electrojet plasma. We recognize, however, that the evidence for electron demagnetization presented in this report cannot be regarded as definitive because it is based on a limited set of data. More experimental research in this direction is thus needed.
-
A short review of recent observations of solar wind fluctuations in the magnetohydrodynamic (MHD) range of scales is presented. In recent years, the use of high time-resolution data on an extended interval of heliocentric distance has allowed significant advances in our knowledge of MHD fluctuations. We first focus on the origin and evolution of the Alfvénic-type fluctuations. The role of interplanetary sources and the influence of interactions with structures convected by the solar wind are examined. Then compressive fluctuations are investigated, with special attention being given to their nature and origin. Observations are discussed in the light of recent theories and models. Finally, predictions for MHD turbulence in polar regions of the heliosphere are highlighted.
-
Based on snow- and ice-thickness measurements at >11 000 points augmented by snow- and icecore studies during 4 expeditions from 1986 - 92 in the Weddell Sea, we describe characteristics and distribution patterns of snow and meteoric ice and assess their importance for the mass balance of sea ice. For first-year ice (FY) in the central and eastern Weddell Sea, mean snow depth amounts to 0.16 m (mean ice thickness 0.75 m) compared to 0.53 m (mean ice thickness 1.70 m) for second-year ice (SY) in the northwestern Weddell Sea. Ridged ice retains a thicker snow cover than level ice, with ice thickness and snow depth negatively correlated for the latter, most likely due to aeolian redistribution. During the different expeditions, 8, 15, 17 and 40% of all drill holes exhibited negative freeboard. As a result of flooding and brine seepage into the snow pack, snow salinities averaged 4‰. Through <sup>18</sup>O measurements the distribution of meteoric ice (i.e. precipitation) in the sea-ice cover was assessed. Roughly 4% of the total ice thickness consist of meteoric ice (FY 3%, SY 5%). With a mean density of 290 kg/m<sup>3</sup>, the snow cover itself contributes 8% to total ice mass (7% FY, 11% SY). Analysis of <i>∆</i><sup>18</sup>O in snow indicates a local maximum in accumulation in the 65 to 75°S latitude zone. Hydrogen peroxide in the snow has proven useful as a temporal tracer and for identification of second-year floes. Drawing on accumulation data from stations at the Weddell Sea coast, it becomes clear that the onset of ice growth is important for the evolution of ice thickness and the interaction between ice and snow. Loss of snow to leads due to wind drift may be considerable, yet is reduced owing to metamorphic processes in the snow column. This is confirmed by a comparison of accumulation data from coastal stations and from snow depths over sea ice. Temporal and spatial accumulation patterns of snow are shown to be important in controlling the sea-ice cover evolution.
-
In situ measurements of the solar wind largely cover more than two solar magnetic activity cycles, namely 20 and 21. This is a very appealing opportunity to study the influence of the activity cycle on the behaviour of the solar wind parameters. As a matter of fact, many authors so far have studied this topic comparing the long-term magnetic field and plasma averages. However, when the average values are evaluated on a data sample whose duration is comparable with (or even longer than) the solar rotation period we lose information about the contribution due to the fast and the slow solar wind components. Thus, discriminating in velocity plays a key role in understanding solar cycle effects on the solar wind. Based on these considerations, we performed a separate analysis for fast and slow wind, respectively. In particular, we found that: (a) fast wind carries a slightly larger momentum flux density at 1 AU, probably due to dynamic stream-stream interaction; (b) proton number density in slow wind is more cycle dependent than in fast wind and decreases remarkably across solar maximum; (c) fast wind generally carries a magnetic field intensity stronger than that carried by the slow wind; (d) we found no evidence for a positive correlation between velocity and field intensity as predicted by some theories of solar wind acceleration; (e) our results would support an approximately constant divergence of field lines associated with corotating high-velocity streams.
