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Ocean-tide parameters from the simultaneous long-period analysis of the orbits of Starlette and Stella

The orbits of two geodetic satellites, Starlette and Stella, have been analysed in order to determine ocean-tide parameters. The orbit of Starlette has been determined over a three-year period and Stella over a one-year period. Long-period analysis techniques have been used to determine the evolutions of the orbital inclination, eccentricity and right ascension of the ascending node for each satellite due to ocean tides. The ocean-tide parameters have been determined in a simultaneous fitting of the theoretical orbital variations to the observed variations. The results are compared with ocean-tide models.
Effect of equatorial ionization anomaly on the occurrence of spread-F

The unique geometry of the geomagnetic field lines over the equatorial ionosphere coupled with the E-W electric field causes the equatorial ionization anomaly (EIA) and equatorial spread-F (ESF). Ionosonde data obtained at a chain of four stations covering equator to anomaly crest region (0.3 to 33 °N dip) in the Indian sector are used to study the role of EIA and the associated processes on the occurrence of ESF. The study period pertains to the equinoctial months (March, April, September and October) of 1991. The ratios of critical frequency of F-layer (ƒ0F2) and electron densities at an altitude of 270 km between Ahmedabad (33 °N dip) and Waltair (20 °N dip) are found to shoot up in the afternoon hours on spread-F days showing strengthening of the EIA in the afternoon hours. The study confirms the earlier conclusions made by Raghava Rao et al. and Alex et al. that a well-developed EIA is one of the conditions conducive for the generation of ESF. This study also shows that the location of the crest is also important in addition to the strength of the anomaly.
Ionospheric and geomagnetic responses to changes in IMF BZ: a superposed epoch study

Superposed epoch studies have been carried out in order to determine the ionospheric response at mid-latitudes to southward turnings of the interplanetary magnetic field (IMF). This is compared with the geomagnetic response, as seen in the indices Kp, AE and Dst. The solar wind, IMF and geomagnetic data used were hourly averages from the years 1967–1989 and thus cover a full 22-year cycle in the solar magnetic field. These data were divided into subsets, determined by the magnitudes of the southward turnings and the concomitant increase in solar wind pressure. The superposed epoch studies were carried out using the time of the southward turning as time zero. The response of the mid-latitude ionosphere is studied by looking at the F-layer critical frequencies, foF2, from hourly soundings by the Slough ionosonde and their deviation from the monthly median values, δfoF2. For the southward turnings with a change in Bz of δBz > 11.5 nT accompanied by a solar wind dynamic pressure P exceeding 5 nPa, the F region critical frequency, foF2, shows a marked decrease, reaching a minimum value about 20 h after the southward turning. This recovers to pre-event values over the subsequent 24 h, on average. The Dst index shows the classic storm-time decrease to about –60 nT. Four days later, the index has still to fully recover and is at about –25 nT. Both the Kp and AE indices show rises before the southward turnings, when the IMF is strongly northward but the solar wind dynamic pressure is enhanced. The average AE index does register a clear isolated pulse (averaging 650 nT for 2 h, compared with a background peak level of near 450 nT at these times) showing enhanced energy deposition at high latitudes in substorms but, like Kp, remains somewhat enhanced for several days, even after the average IMF has returned to zero after 1 day. This AE background decays away over several days as the Dst index recovers, indicating that there is some contamination of the currents observed at the AE stations by the continuing enhanced equatorial ring current. For data averaged over all seasons, the critical frequencies are depressed at Slough by 1.3 MHz, which is close to the lower decile of the overall distribution of δfoF2 values. Taking 30-day periods around summer and winter solstice, the largest depression is 1.6 and 1.2 MHz, respectively. This seasonal dependence is confirmed by a similar study for a Southern Hemisphere station, Argentine Island, giving peak depressions of 1.8 MHz and 0.5 MHz for summer and winter. For the subset of turnings where δBz > 11.5 nT and P ≤ 5 nPa, the response of the geomagnetic indices is similar but smaller, while the change in δfoF2 has all but disappeared. This confirms that the energy deposited at high latitudes, which leads to the geomagnetic and ionospheric disturbances following a southward turning of the IMF, increases with the energy density (dynamic pressure) of the solar wind flow. The magnitude of all responses are shown to depend on δBz. At Slough, the peak depression always occurs when Slough rotates into the noon sector. The largest ionospheric response is for southward turnings seen between 15–21 UT.
Uncertainties in field-line tracing in the magnetosphere. Part II: the complete internal geomagnetic field

The discussion in the preceding paper is restricted to the uncertainties in magnetic-field-line tracing in the magnetosphere resulting from published standard errors in the spherical harmonic coefficients that define the axisymmetric part of the internal geomagnetic field (i.e. gn0 ± δgn0). Numerical estimates of these uncertainties based on an analytic equation for axisymmetric field lines are in excellent agreement with independent computational estimates based on stepwise numerical integration along magnetic field lines. This comparison confirms the accuracy of the computer program used in the present paper to estimate the uncertainties in magnetic-field-line tracing that arise from published standard errors in the full set of spherical harmonic coefficients, which define the complete (non-axisymmetric) internal geomagnetic field (i.e. gnm ± δgnm and hnm ± δhnm). An algorithm is formulated that greatly reduces the computing time required to estimate these uncertainties in magnetic-field-line tracing. The validity of this algorithm is checked numerically for both the axisymmetric part of the internal geomagnetic field in the general case (1 ≤ n ≤ 10) and the complete internal geomagnetic field in a restrictive case (0 ≤ m ≤ n, 1 ≤ n ≤ 3). On this basis it is assumed that the algorithm can be used with confidence in those cases for which the computing time would otherwise be prohibitively long. For the complete internal geomagnetic field, the maximum characteristic uncertainty in the geocentric distance of a field line that crosses the geomagnetic equator at a nominal dipolar distance of 2 RE is typically 100 km. The corresponding characteristic uncertainty for a field line that crosses the geomagnetic equator at a nominal dipolar distance of 6 RE is typically 500 km. Histograms and scatter plots showing the characteristic uncertainties associated with magnetic-field-line tracing in the magnetosphere are presented for a range of illustrative examples. Finally, estimates are given for the maximum uncertainties in the locations of the conjugate points of selected geophysical observatories. Numerical estimates of the uncertainties in magnetic-field-line tracing in the magnetosphere, including the associated uncertainties in the locations of the conjugate points of geophysical observatories, should be regarded as "first approximations' in the sense that these estimates are only as accurate as the published standard errors in the full set of spherical harmonic coefficients. As in the preceding paper, however, all computational techniques developed in this paper can be used to derive more realistic estimates of the uncertainties in magnetic-field-line tracing in the magnetosphere, following further progress in the determination of more accurate standard errors in the spherical harmonic coefficients.
Determination of the dispersion of low frequency waves downstream of a quasiperpendicular collisionless shock

A method of wave mode determination, which was announced in Balikhin and Gedalin, is applied to AMPTE UKS and AMPTE IRM magnetic field measurements downstream of supercritical quasiperpendicular shock. The method is based on the fact that the relation between phase difference of the waves measured by two satellites, Doppler shift equation, the direction of the wave propagation are enough to obtain the dispersion equation of the observed waves. It is shown that the low frequency turbulence mainly consists of waves observed below 1 Hz with a linear dependence between the absolute value of wave vector |k| and the plasma frame wave frequency. The phase velocity of these waves is close to the phase velocity of intermediate waves Vint = Vacos(θ).
Air–surface exchange of gaseous mercury over permafrost soil: an investigation at a high-altitude (4700 m a.s.l.) and remote site in the central Qinghai–Tibet Plateau

The pattern of air–surface gaseous mercury (mainly Hg(0)) exchange in the Qinghai–Tibet Plateau (QTP) may be unique because this region is characterized by low temperature, great temperature variation, intensive solar radiation, and pronounced freeze–thaw process of permafrost soils. However, the air–surface Hg(0) flux in the QTP is poorly investigated. In this study, we performed field measurements and controlled field experiments with dynamic flux chambers technique to examine the flux, temporal variation and influencing factors of air–surface Hg(0) exchange at a high-altitude (4700 m a.s.l.) and remote site in the central QTP. The results of field measurements showed that surface soils were the net emission source of Hg(0) in the entire study (2.86 ng m−2 h−1 or 25.05 µg m−2 yr−1). Hg(0) flux showed remarkable seasonality with net high emission in the warm campaigns (June 2014: 4.95 ng m−2 h−1; September 2014: 5.16 ng m−2 h−1; and May–June 2015: 1.95 ng m−2 h−1) and net low deposition in the winter campaign (December 2014: −0.62 ng m−2 h−1) and also showed a diurnal pattern with emission in the daytime and deposition in nighttime, especially on days without precipitation. Rainfall events on the dry soils induced a large and immediate increase in Hg(0) emission. Snowfall events did not induce the pulse of Hg(0) emission, but snowmelt resulted in the immediate increase in Hg(0) emission. Daily Hg(0) fluxes on rainy or snowy days were higher than those of days without precipitation. Controlled field experiments suggested that water addition to dry soils significantly increased Hg(0) emission both on short (minutes) and relatively long (hours) timescales, and they also showed that UV radiation was primarily attributed to Hg(0) emission in the daytime. Our findings imply that a warm climate and environmental change could facilitate Hg release from the permafrost terrestrial ecosystem in the QTP.
Regional and local variations in atmospheric aerosols using ground-based sun photometry during Distributed Regional Aerosol Gridded Observation Networks (DRAGON) in 2012

Aerosol mass concentrations are affected by local emissions as well as long-range transboundary (LRT) aerosols. This work investigates regional and local variations of aerosols based on Distributed Regional Aerosol Gridded Observation Networks (DRAGON). We constructed DRAGON-Japan and DRAGON-Osaka in spring of 2012. The former network covers almost all of Japan in order to obtain aerosol information in regional scale over Japanese islands. It was determined from the DRAGON-Japan campaign that the values of aerosol optical thickness (AOT) decrease from west to east during an aerosol episode. In fact, the highest AOT was recorded at Fukue Island at the western end of the network, and the value was much higher than that of urban areas. The latter network (DRAGON-Osaka) was set as a dense instrument network in the megalopolis of Osaka, with a population of 12 million, to better understand local aerosol dynamics in urban areas. AOT was further measured with a mobile sun photometer attached to a car. This transect information showed that aerosol concentrations rapidly changed in time and space together when most of the Osaka area was covered with moderate LRT aerosols. The combined use of the dense instrument network (DRAGON-Osaka) and high-frequency measurements provides the motion of aerosol advection, which coincides with the wind vector around the layer between 700 and 850 hPa as provided by the reanalysis data of the National Centers for Environmental Prediction (NCEP).
Modeling investigation of light-absorbing aerosols in the Amazon Basin during the wet season

We use a global chemical transport model (GEOS-Chem) to interpret observed light-absorbing aerosols in Amazonia during the wet season. Observed aerosol properties, including black carbon (BC) concentration and light absorption, at the Amazon Tall Tower Observatory (ATTO) site in the central Amazon have relatively low background levels but frequently show high peaks during the study period of January–April 2014. With daily temporal resolution for open fire emissions and modified aerosol optical properties, our model successfully captures the observed variation in fine/coarse aerosol and BC concentrations as well as aerosol light absorption and its wavelength dependence over the Amazon Basin. The source attribution in the model indicates the important influence of open fire on the observed variances of aerosol concentrations and absorption, mainly from regional sources (northern South America) and from northern Africa. The contribution of open fires from these two regions is comparable, with the latter becoming more important in the late wet season. The analysis of correlation and enhancement ratios of BC versus CO suggests transport times of < 3 days for regional fires and ∼  11 days for African plumes arriving at ATTO during the wet season. The model performance of long-range transport of African plumes is also evaluated with observations from AERONET, MODIS, and CALIOP. Simulated absorption aerosol optical depth (AAOD) averaged over the wet season is lower than 0.0015 over the central Amazon, including the ATTO site. We find that more than 50 % of total absorption at 550 nm is from BC, except for the northeastern Amazon and the Guianas, where the influence of dust becomes significant (up to 35 %). The brown carbon contribution is generally between 20 and 30 %. The distribution of absorption Ångström exponents (AAE) suggests more influence from fossil fuel combustion in the southern part of the basin (AAE ∼  1) but more open fire and dust influence in the northern part (AAE > 1.8). Uncertainty analysis shows that accounting for absorption due to secondary organic aerosol (SOA) and primary biogenic aerosol (PBA) particles could result in differences of < 8 and 5–40 % in total absorption, respectively.
Impacts of global open-fire aerosols on direct radiative, cloud and surface-albedo effects simulated with CAM5

Aerosols from open-land fires could significantly perturb the global radiation balance and induce climate change. In this study, Community Atmosphere Model version 5 (CAM5) with prescribed daily fire aerosol emissions is used to investigate the spatial and seasonal characteristics of radiative effects (REs, relative to the case of no fires) of open-fire aerosols including black carbon (BC) and particulate organic matter (POM) from 2003 to 2011. The global annual mean RE from aerosol–radiation interactions (REari) of all fire aerosols is 0.16 ± 0.01 W m−2 (1σ uncertainty), mainly due to the absorption of fire BC (0.25 ± 0.01 W m−2), while fire POM induces a small effect (−0.05 and 0.04 ± 0.01 W m−2 based on two different methods). Strong positive REari is found in the Arctic and in the oceanic regions west of southern Africa and South America as a result of amplified absorption of fire BC above low-level clouds, in general agreement with satellite observations. The global annual mean RE due to aerosol–cloud interactions (REaci) of all fire aerosols is −0.70 ± 0.05 W m−2, resulting mainly from the fire POM effect (−0.59 ± 0.03 W m−2). REari (0.43 ± 0.03 W m−2) and REaci (−1.38 ± 0.23 W m−2) in the Arctic are stronger than in the tropics (0.17 ± 0.02 and −0.82 ± 0.09 W m−2 for REari and REaci), although the fire aerosol burden is higher in the tropics. The large cloud liquid water path over land areas and low solar zenith angle of the Arctic favor the strong fire aerosol REaci (up to −15 W m−2) during the Arctic summer. Significant surface cooling, precipitation reduction and increasing amounts of low-level cloud are also found in the Arctic summer as a result of the fire aerosol REaci based on the atmosphere-only simulations. The global annual mean RE due to surface-albedo changes (REsac) over land areas (0.03 ± 0.10 W m−2) is small and statistically insignificant and is mainly due to the fire BC-in-snow effect (0.02 W m−2) with the maximum albedo effect occurring in spring (0.12 W m−2) when snow starts to melt.
Temporal variability and sources of VOCs in urban areas of the eastern Mediterranean

During the summer of 2012 volatile organic compounds (VOCs) were monitored by proton transfer reaction mass spectrometry (PTR-MS) in urban sites, in Athens and Patras, two of the largest cities in Greece. Also, during the winter of 2013, PTR-MS measurements were conducted in the center of the city of Athens. Positive matrix factorization (PMF) was applied to the VOC measurements to gain insights about their sources. In summer most of the measured VOCs were due to biogenic and traffic emissions. Isoprene, monoterpenes, and several oxygenated VOCs (oVOCs) originated mainly from vegetation either directly or as oxidation products. Isoprene average concentrations in Patras and Athens were 1 and 0.7 ppb respectively, while the monoterpene concentrations were 0.3 and 0.9 ppb respectively. Traffic was the main source of aromatic compounds during summer. For Patras and Athens the average concentrations of benzene were 0.1 and 0.2 ppb, of toluene 0.3 and 0.8 ppb, and of the xylenes 0.3 and 0.7 ppb respectively. Winter measurements in Athens revealed that biomass burning used for residential heating was a major VOC source contributing both aromatic VOCs and biogenic compounds such as monoterpenes. Several episodes related to biomass burning were identified and emission ratios (ERs) and emission factors (EFs) were estimated.