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Recently, one of the authors (A. V. G.) developed a theory of low-frequency plasma irregularities which are created as a consequence of neutral turbulence in the D and lower E regions. In the following this theory will be applied to coherent backscatter experiments with radars in a frequency range between 5 and 150 MHz. We discuss the dependence of the backscatter cross-section on ionospheric as well as on turbulence parameters. The backscatter increases strongly with decreasing radar frequency. Above 15 MHz the effects discussed here can probably only be detected by very powerful radars with large antenna arrays.
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Many measurements have shown that the random temperature fields in the stably stratified atmosphere are not locally isotropic (LI). The local axial symmetry (LAS) hypothesis looks more appropriate under these conditions. The object of this paper consists in the development of a flexible tool for spectral studies of LAS scalar fields independently of their origin in stably stratified geophysical flows. A heuristic model of a 3D spatial spectrum is proposed in order to describe and study statistical properties of LAS temperature inhomogeneities from LI structures up to quasi-layered ones. To simplify the solution of this problem, a main assumption was accepted: the consideration is restricted to 3D spectra which may be given on a one-parametric family of surfaces of rotation. Such 3D spectra may be represented by a single function of one variable which is the parameter of the family. This approach allows one to introduce the generalized energy spectrum which describes an energy distribution according to inhomogeneity sizes. The family of surfaces determines the shape of inhomogeneities. The family of ellipsoids of rotation and power-law generalized energy spectrum is used as the simplest example of the model application in order to study the general properties of LAS-structure spectra. The behavior of vertical, horizontal, and oblique 1D spectra and coherency spectra is studied. The relationship between the suggested model and some existing models of temperature spectra is considered. The application of the model for the analysis of experimental data is shown for two sets of measurements. It is shown that the suggested model may quantitatively describe experimental 1D spectra and coherency spectra from a unique point of view. It is noted that the model may be used for both the planning of measurements and data processing. Possible generalizations of the model are considered for random fields with more degenerate symmetry and for space-temporal spectra.
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Measurements of the slope current at two locations north-west of Ireland have been made between April and December 1994, 40 m above the seabed in a water depth of 660 m. A persistent poleward along-slope current was observed at both locations, with measured means of 10 and 21cms<sup>–1</sup> respectively. A CTD transect across the slope near one mooring indicated the presence of a light, warm, saline core of water at the shelf edge. Peak currents were <i>O</i>(50)cms<sup>–1</sup>, with strongest mean flow at the location with steeper slope. Variability at sub-tidal periods, principally 2–5 and 11–12 days, was apparent. The shorter-period variability was well correlated with coastal sea-level variations measured at a land point near to one of the moorings. The variability in the slope current at this period appeared to be a result of the warm current core movement up/down slope, probably as a result of interaction with higher-mode shelf waves. Some suggestion of a bottom-trapped diurnal wave was also found at one location.
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This study compares the OV1-10 satellite measurements of the integral airglow intensities at 630 nm in the SAR arc regions observed in the northern and southern hemisphere as a conjugate phenomenon, with the model results obtained using the time-dependent one-dimensional mathematical model of the Earth ionosphere and plasmasphere (the IZMIRAN model) during the geomagnetic storm of the period 15–17 February 1967. The major enhancements to the IZMIRAN model developed in this study are the inclusion of He<sup>+</sup> ions (three major ions: O<sup>+</sup>, H<sup>+</sup>, and He<sup>+</sup>, and three ion temperatures), the updated photochemistry and energy balance equations for ions and electrons, the diffusion of NO<sup>+</sup> and O<sub>2</sub><sup>+</sup> ions and O(<sup>1</sup>D) and the revised electron cooling rates arising from their collisions with unexcited N<sub>2</sub>, O<sub>2</sub> molecules and N<sub>2</sub> molecules at the first vibrational level. The updated model includes the option to use the models of the Boltzmann or non-Boltzmann distributions of vibrationally excited molecular nitrogen. Deviations from the Boltzmann distribution for the first five vibrational levels of N<sub>2</sub> were calculated. The calculated distribution is highly non-Boltzmann at vibrational levels <i>v </i>> 2 and leads to a decrease in the calculated electron density and integral intensity at 630 nm in the northern and southern hemispheres in comparison with the electron density and integral intensity calculated using the Boltzmann vibrational distribution of N<sub>2</sub>. It is found that the intensity at 630 nm is very sensitive to the oxygen number densities. Good agreement between the modelled and measured intensities is obtained provided that at all altitudes of the southern hemisphere a reduction of about factor 1.35 in MSIS-86 atomic oxygen densities is included in the IZMIRAN model with the non-Boltzmann vibrational distribution of N<sub>2</sub>. The effect of using of the O(<sup>1</sup>D) diffusion results in the decrease of 4–6% in the calculated integral intensity of the northern hemisphere and 7–13% in the calculated integral intensity of the southern hemisphere. It is found that the modelled intensities of the southern hemisphere are more sensitive to the assumed values of the rate coefficients of O<sup>+</sup>(<sup>4</sup>S) ions with the vibrationally excited nitrogen molecules and quenching of O<sup>+</sup>(<sup>2</sup>D) by atomic oxygen than the modelled intensities of the northern hemisphere.
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The FORCAsT canopy exchange model was used to investigate the underlying mechanisms governing foliage emissions of methanol and acetaldehyde, two short chain oxygenated volatile organic compounds ubiquitous in the troposphere and known to have strong biogenic sources, at a northern mid-latitude forest site. The explicit representation of the vegetation canopy within the model allowed us to test the hypothesis that stomatal conductance regulates emissions of these compounds to an extent that its influence is observable at the ecosystem scale, a process not currently considered in regional- or global-scale atmospheric chemistry models.<br><br>We found that FORCAsT could only reproduce the magnitude and diurnal profiles of methanol and acetaldehyde fluxes measured at the top of the forest canopy at Harvard Forest if light-dependent emissions were introduced to the model. With the inclusion of such emissions, FORCAsT was able to successfully simulate the observed bidirectional exchange of methanol and acetaldehyde. Although we found evidence that stomatal conductance influences methanol fluxes and concentrations at scales beyond the leaf level, particularly at dawn and dusk, we were able to adequately capture ecosystem exchange without the addition of stomatal control to the standard parameterisations of foliage emissions, suggesting that ecosystem fluxes can be well enough represented by the emissions models currently used.
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Effects of the Quasi-Biennial Oscillation (QBO) on tropospheric climate are not always strong or they appear only intermittently. Studying them requires long time series of both the QBO and climate variables, which has restricted previous studies to the past 30–50 years. Here we use the benefits of an existing QBO reconstruction back to 1908. We first investigate additional, newly digitized historical observations of stratospheric winds to test the reconstruction. Then we use the QBO time series to analyse atmospheric data sets (reconstructions and reanalyses) as well as the results of coupled ocean–atmosphere–chemistry climate model simulations that were forced with the reconstructed QBO. We investigate effects related to (1) tropical–extratropical interaction in the stratosphere, wave–mean flow interaction and subsequent downward propagation, and (2) interaction between deep tropical convection and stratospheric flow. We generally find weak connections, though some are statistically significant over the 100-year period and consistent with model results. Apparent multidecadal variations in the connection between the QBO and the investigated climate responses are consistent with a small effect in the presence of large variability, with one exception: the imprint on the northern polar vortex, which is seen in recent reanalysis data, is not found in the period 1908–1957. Conversely, an imprint in Berlin surface air temperature is only found in 1908–1957 but not in the recent period. Likewise, in the model simulations both links tend to appear alternatingly, suggesting a more systematic modulation due to a shift in the circulation, for example. Over the Pacific warm pool, we find increased convection during easterly QBO, mainly in boreal winter in observation-based data as well as in the model simulations, with large variability. No QBO effects were found in the Indian monsoon strength or Atlantic hurricane frequency.
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The multilinear engine (ME-2) factorization tool is being widely used following the recent development of the Source Finder (SoFi) interface at the Paul Scherrer Institute. However, the success of this tool, when using the <i>a</i> value approach, largely depends on the inputs (i.e. target profiles) applied as well as the experience of the user. A strategy to explore the solution space is proposed, in which the solution that best describes the organic aerosol (OA) sources is determined according to the systematic application of predefined statistical tests. This includes trilinear regression, which proves to be a useful tool for comparing different ME-2 solutions. Aerosol Chemical Speciation Monitor (ACSM) measurements were carried out at the urban background site of North Kensington, London from March to December 2013, where for the first time the behaviour of OA sources and their possible environmental implications were studied using an ACSM. Five OA sources were identified: biomass burning OA (BBOA), hydrocarbon-like OA (HOA), cooking OA (COA), semivolatile oxygenated OA (SVOOA) and low-volatility oxygenated OA (LVOOA). ME-2 analysis of the seasonal data sets (spring, summer and autumn) showed a higher variability in the OA sources that was not detected in the combined March–December data set; this variability was explored with the triangle plots <i>f</i>44 : <i>f</i>43 <i>f</i>44 : <i>f</i>60, in which a high variation of SVOOA relative to LVOOA was observed in the <i>f</i>44 : <i>f</i>43 analysis. Hence, it was possible to conclude that, when performing source apportionment to long-term measurements, important information may be lost and this analysis should be done to short periods of time, such as seasonally. Further analysis on the atmospheric implications of these OA sources was carried out, identifying evidence of the possible contribution of heavy-duty diesel vehicles to air pollution during weekdays compared to those fuelled by petrol.
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The North Atlantic Oscillation (NAO) plays an important role in the climate variability of the Northern Hemisphere, with significant consequences on long-range pollutant transport. We investigate the evolution of pollutant transport in the 21st century influenced by the NAO under a global climate change scenario. We use a free-running simulation performed by the ECHAM/MESSy Atmospheric Chemistry (EMAC) model coupled with the ocean general circulation model MPIOM, covering the period from 1950 until 2100. Similarly to other works, the model shows a future northeastward shift of the NAO centres of action and a weak positive trend of the NAO index (over 150 years). Moreover, we find that NAO trends (computed over periods shorter than 30 years) will continue to oscillate between positive and negative values in the future. To investigate the NAO effects on transport we consider carbon monoxide tracers with exponential decay and constant interannual emissions. We find that at the end of the century, the south-western Mediterranean and northern Africa will, during positive NAO phases, see higher pollutant concentrations with respect to the past, while a wider part of northern Europe will, during positive NAO phases, see lower pollutant concentrations. Such results are confirmed by the changes observed in the future for tracer concentration and vertically integrated tracer transport, differentiating the cases of “high NAO” and “low NAO” events.
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A chemical reaction chamber system has been developed for the processing of oleic acid aerosol particles with ozone under two relative humidity conditions: dry and humidified to 65 %. The apparatus consists of an aerosol flow tube, in which the ozonolysis occurs, coupled to a scanning mobility particle sizer (SMPS) and an aerosol time-of-flight mass spectrometer (ATOFMS) which measure the evolving particle size and composition. Under both relative humidity conditions, ozonolysis results in a significant decrease in particle size and mass which is consistent with the formation of volatile products that partition from the particle to the gas phase. Mass spectra derived from the ATOFMS reveal the presence of the typically observed reaction products: azelaic acid, nonanal, oxononanoic acid and nonanoic acid, as well as a range of higher molecular weight products deriving from the reactions of reaction intermediates with oleic acid and its oxidation products. These include octanoic acid and 9- and 10-oxooctadecanoic acid, as well as products of considerably higher molecular weight. Quantitative evaluation of product yields with the ATOFMS shows a marked dependence upon both particle size association (from 0.3 to 2.1 µm diameter) and relative humidity. Under both relative humidity conditions, the percentage residual of oleic acid increases with increasing particle size and the main lower molecular weight products are nonanal and oxononanoic acid. Under dry conditions, the percentage of higher molecular weight products increases with increasing particle size due to the poorer internal mixing of the larger particles. Under humidified conditions, the percentage of unreacted oleic acid is greater, except in the smallest particle fraction, with little formation of high molecular weight products relative to the dry particles. It is postulated that water reacts with reactive intermediates, competing with the processes which produce high molecular weight products. Whilst the oleic acid model aerosol system is of limited relevance to complex internally mixed atmospheric aerosol, the generic findings presented in this paper give useful insights into the nature of heterogeneous chemical processes.
