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Latent heat release associated with tropical deep convective activity is investigated as a source for migrating (sun-synchronous) diurnal and semidiurnal tidal oscillations in the 80–150-km height region. Satellite-based cloud brightness temperature measurements made between 1988 and 1994 and averaged into 3-h bins are used to determine the annual- and longitude-average local-time distribution of rainfall rate, and hence latent heating, between ±40° latitude. Regional average rainfall rates are shown to be in good agreement with climatological values derived from surface rain gauge data. A global linearized wave model is used to estimate the corresponding atmospheric perturbations in the mesosphere/lower thermosphere (80–150 km) resulting from upward-propagating tidal components excited by the latent heating. The annual-average migrating diurnal and semidiurnal components achieve velocity and temperature amplitudes of order 10–20 m s<sup>–1</sup> and 5–10 K, respectively, which represent substantial contributions to the dynamics of the region. The latent heat forcing also shifts the phase (local solar time of maximum) of the semidiurnal surface pressure oscillation from 0912 to 0936 h, much closer to the observed value of 0944 h.
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The Global-Scale Wave Model (GSWM) is a steady-state two-dimensional linearized model capable of simulating the solar tides and planetary waves. In an effort to understand the capabilities and limitations of the GSWM throughout the upper mesosphere and thermosphere a comparative analysis with observational data is presented. A majority of the observational data used in this study was collected during the World Day campaign which ran from 20 January to 30 January 1993. During this campaign data from 18 ground-based observational sites across the globe and two instruments located on the UARS spacecraft were analyzed. Comparisons of these data with the simulations from the GSWM indicate that the GSWM results are in reasonable agreement with the observations. However, there are a number of cases where the agreement is not particularly good. One such instance is for the semidiurnal tide in the northern hemisphere, where the GSWM estimates may exceed observations by 50% . Through a number of numerical simulations, it appears that this discrepancy may be due to the eddy diffusivity profiles used by the GSWM. Other differences relating to the diurnal tide and the quasi-two-day wave are presented and discussed. Additionally, a discussion on the biases and aliasing difficulties which may arise in the observational data is also presented.
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We explore tropospheric latent heat release as a source of variability of the diurnal tide in the mesosphere and lower thermosphere (MLT) in two ways. First, we present analyses of the UARS WINDII horizontal wind data, which reveal signatures of nonmigrating tidal effects as large as 25 m/s during both vernal equinox and boreal winter. These effects are of greater relative importance during the latter season. Complementary global-scale wave model (GSWM) results which account for a tropospheric latent heat source generally underestimate the observed nonmigrating tidal effects but capture the seasonal variability that is observed. Second, we pursue a new parameterization scheme to investigate seasonal variability of the migrating diurnal tidal component of the latent heat source with GSWM. These results confirm previously reported seasonal trends, but suggest that the MLT effects may be as much as an order of magnitude larger than earlier predictions.
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Wind and temperature observations in the mesosphere and lower thermosphere (MLT) from the Upper Atmosphere Research Satellite (UARS) reveal strong seasonal variations of tides, a dominant component of the MLT dynamics. Simulations with the Spectral mesosphere/lower thermosphere model (SMLTM) for equinox and solstice conditions are presented and compared with the observations. The diurnal tide is generated by forcing specified at the model lower boundary and by in situ absorption of solar radiation. The model incorporates realistic parameterizations of physical processes including various dissipation processes important for propagation of tidal waves in the MLT. A discrete multi-component gravity-wave parameterization has been modified to account for seasonal variations of the background temperature. Eddy diffusion is calculated depending on the gravity-wave energy deposition rate and stability of the background flow. It is shown that seasonal variations of the diurnal-tide amplitudes are consistent with observed variations of gravity-wave sources in the lower atmosphere.
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Monthly simulations of the thermal diurnal and semidiurnal tides are compared to High-Resolution Doppler Imager (HRDI) and Wind Imaging Interferometer (WINDII) wind and temperature measurements on the Upper-Atmosphere Research Satellite (UARS). There is encouraging agreement between the observations and the linear global mechanistic tidal model results both for the diurnal and semidiurnal components in the equatorial and mid-latitude regions. This gives us the confidence to outline the first steps of an assimilative analysis/interpretation for tides, dissipation, and mean flow using a combination of model results and the global measurements from HRDI and WINDII. The sensitivity of the proposed technique to the initial guess employed to obtain a best fit to the data by tuning model parameters is discussed for the January and March 1993 cases, when the WINDII day and night measurements of the meridional winds between 90 and 110 km are used along with the daytime HRDI measurements. Several examples for the derivation of the tidal variables and decomposition of the measured winds into tidal and mean flow components using this approach are compared with previous tidal estimates and modeling results for the migrating tides. The seasonal cycle of the derived diurnal tidal amplitudes are discussed and compared with radar observation between 80 and 100 km and 40<sup>°</sup>S and 40<sup>°</sup>N.
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This paper uses dissipation values derived from UARS/HRDI observations in a recently published diurnal-tide model. These model structures compare quite well with the UARS/HRDI observations with respect to the annual variation of the diurnal tidal amplitudes and the size of the amplitudes themselves. It is suggested that the annual variation of atmospheric dissipation in the mesosphere-lower thermosphere is a major controlling factor in determining the annual variation of the diurnal tide.
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Detailed comparisons have been completed between the MF radars (MFR) in the Canadian prairies and three other systems: two ground-based Fabry-Perot interferometers (FPI) and the UARS high resolution Doppler imager (HRDI) system. The radars were at Sylvan Lake (52<sup>°</sup>N, 114<sup>°</sup>W), Robsart <br> (49<sup>°</sup>N, 109<sup>°</sup>W) and the main continuing facility is at Saskatoon (52<sup>°</sup>N, 107<sup>°</sup>W). Statistical comparisons of hourly mean winds (1988-1992) for the Saskatoon MFR and FPI (557.7 nm green line) using scatter plots, wind speed-ratios, and direction-difference histograms show excellent agreement for Saskatoon. No serious biases in speeds or directions occur at the height of best agreement, 98 km. If anything, the MFR speeds appear bigger. The same applies to the Sylvan Lake MFR and Calgary FPI, where the best height is 88 km. In both cases these are close to the preferred heights for the emission layers. Differences between measurements seen on individual days are likely related to the influence of gravity waves (GW) upon the optical and radar systems, each of which have inherent spatial averaging (350, 50 km respectively), as well as the spatial difference between the nominal measurement locations. For HRDI, similar statistical comparisons are made, using single-overpass satellite winds and hourly means (to improve data quality) from MFR. Heights of best agreement, based upon direction-difference histograms, are shown; there is a tendency, beginning near 87 km, for these MFR heights to be 2 or 3 km greater than the HRDI heights. Speeds at these heights are typically larger for the satellite (MFR/HRDI = 0.7–0.8). Reasons for the differences are investigated. It is shown that the estimated errors and short-term (90 min) differences are larger for HRDI than for the MFR, indicating more noise or GW contamination. This leads to modest but significant differences in median speed-ratio (MFR/HRDI < 1). Also, comparison of the two systems is made under conditions when they agree best and when they show large disagreement. For the latter cases both systems show higher relative errors, and the HRDI vectors are frequently small. It is suggested that spatial or temporal GW wind fluctuations are the likely cause of the larger HRDI-MFR disagreement when wind speeds are small. No satisfactory explanation exists for the overall discrepancy in speeds between the MFR and HRDI.
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The widespread use of Aerodyne aerosol mass spectrometers (AMS) has greatly improved real-time organic aerosol (OA) monitoring, providing mass spectra that contain sufficient information for source apportionment. However, AMS field deployments remain expensive and demanding, limiting the acquisition of long-term datasets at many sampling sites. The offline application of aerosol mass spectrometry entailing the analysis of nebulized water extracted filter samples (offline-AMS) increases the spatial coverage accessible to AMS measurements, being filters routinely collected at many stations worldwide. <br><br> PM<sub>1</sub> (particulate matter with an aerodynamic diameter < 1 µm) filter samples were collected during an entire year in Lithuania at three different locations representative of three typical environments of the southeast Baltic region: Vilnius (urban background), Rūgšteliškis (rural terrestrial), and Preila (rural coastal). Aqueous filter extracts were nebulized in Ar, yielding the first AMS measurements of water-soluble atmospheric organic aerosol (WSOA) without interference from air fragments. This enables direct measurement of the CO<sup>+</sup> fragment contribution, whose intensity is typically assumed to be equal to that of CO<sub>2</sub><sup>+</sup>. Offline-AMS spectra reveal that the water-soluble CO<sub>2</sub><sup>+</sup> : CO<sup>+</sup> ratio not only shows values systematically > 1 but is also dependent on season, with lower values in winter than in summer. <br><br> AMS WSOA spectra were analyzed using positive matrix factorization (PMF), which yielded four factors. These factors included biomass burning OA (BBOA), local OA (LOA) contributing significantly only in Vilnius, and two oxygenated OA (OOA) factors, summer OOA (S-OOA) and background OOA (B-OOA), distinguished by their seasonal variability. The contribution of traffic exhaust OA (TEOA) was not resolved by PMF due to both low concentrations and low water solubility. Therefore, the TEOA concentration was estimated using a chemical mass balance approach, based on the concentrations of hopanes, specific markers of traffic emissions. AMS-PMF source apportionment results were consistent with those obtained from PMF applied to marker concentrations (i.e., major inorganic ions, OC / EC, and organic markers including polycyclic aromatic hydrocarbons and their derivatives, hopanes, long-chain alkanes, monosaccharides, anhydrous sugars, and lignin fragmentation products). OA was the largest fraction of PM<sub>1</sub> and was dominated by BBOA during winter with an average concentration of 2 µg m<sup>−3</sup> (53 % of OM), while S-OOA, probably related to biogenic emissions, was the prevalent OA component during summer with an average concentration of 1.2 µg m<sup>−3</sup> (45 % of OM). <br><br> PMF ascribed a large part of the CO<sup>+</sup> explained variability (97 %) to the OOA and BBOA factors. Accordingly, we discuss a new CO<sup>+</sup> parameterization as a function of CO<sub>2</sub><sup>+</sup> and C<sub>2</sub>H<sub>4</sub>O<sub>2</sub><sup>+</sup> fragments, which were selected to describe the variability of the OOA and BBOA factors.</p>
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This study examines how new particle formation (NPF) in the eastern Mediterranean in summer affects CCN (cloud condensation nuclei) concentrations and cloud droplet formation. For this, the concentration and size distribution of submicron aerosol particles, along with the concentration of trace gases and meteorological variables, were studied over the central (Santorini) and southern Aegean Sea (Finokalia, Crete) from 15 to 28 July 2013, a period that includes Etesian events and moderate northern surface winds. Particle nucleation bursts were recorded during the Etesian flow at both stations, with those observed at Santorini reaching up to 1.5 × 10<sup>4</sup> particles cm<sup>−3</sup>; the fraction of nucleation-mode particles over Crete was relatively diminished, but a higher number of Aitken-mode particles were observed as a result of aging. Aerosol and photochemical pollutants covaried throughout the measurement period; lower concentrations were observed during the period of Etesian flow (e.g., 43–70 ppbv for ozone and 1.5–5.7 µg m<sup>−3</sup> for sulfate) but were substantially enhanced during the period of moderate surface winds (i.e., increase of up to 32 for ozone and 140 % for sulfate). We find that NPF can double CCN number (at 0.1 % supersaturation), but the resulting strong competition for water vapor in cloudy updrafts decreases maximum supersaturation by 14 % and augments the potential droplet number only by 12 %. Therefore, although NPF events may strongly elevate CCN numbers, the relative impacts on cloud droplet number (compared to pre-event levels) is eventually limited by water vapor availability and depends on the prevailing cloud formation dynamics and the aerosol levels associated with the background of the region.
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The relative importance of eastern Mediterranean emissions is suspected to be largely underestimated compared to other regions worldwide. Here we use detailed speciated measurements of volatile organic compounds (VOCs) to evaluate the spatial heterogeneity of VOC urban emission composition and the consistency of regional and global emission inventories downscaled to Lebanon (European Monitoring and Evaluation Programme, EMEP; Atmospheric Chemistry and Climate Model Intercomparison Project, ACCMIP; and MACCity, Monitoring Atmospheric Composition and Climate and megaCITY Zoom for the Environment). The assessment was conducted through the comparison of the emission ratios (ERs) extracted from the emission inventories to the ones obtained from the hourly observations collected at a suburban site in Beirut, Lebanon, during summer and winter ECOCEM (Emissions and Chemistry of Organic Carbon in the Eastern Mediterranean) campaigns. The observed ERs were calculated using two independent methods. ER values from both methods agree very well and are comparable to the ones of the road transport sector from near-field measurements for more than 80 % of the species. There is no significant seasonality in ER for more than 90 % of the species, unlike the seasonality usually observed in other cities worldwide. Regardless of the season, ERs agree within a factor of 2 between Beirut and other representative cities worldwide, except for the unburned fuel fraction and ethane. ERs of aromatics (except benzene) are higher in Beirut compared to northern post-industrialized countries and even the Middle Eastern city Mecca. The comparison of the observed ER to the ones extracted from the ACCMIP and MACCity global emission inventories suggests that the overall speciation of anthropogenic sources for major hydrocarbons that act as ozone and secondary organic aerosol (SOA) precursors in ACCMIP is better represented than other species. <br><br> The comparison of the specific road transport ERs, relative to acetylene derived from near-field measurements, to ERs from ACCMIP and EMEP emission inventories for the road transport sector showed that ERs of more reactive species are usually consistent within a factor of 2 with EMEP, while xylenes and toluene are underestimated by over a factor of 2 by ACCMIP. <br><br> The observed heterogeneity of anthropogenic VOC emission composition between Middle Eastern cities can be significant for reactive VOCs but is not depicted by global emission inventories. This suggests that systematic and detailed measurements are needed in the eastern Mediterranean Basin in order to better constrain emission inventory.
